Inhaltszusammenfassung

The title compound, [Cu(C5H9N)(4)] Cl (.) H2O, was obtained from the reaction of copper(II) chloride hydrate with KCN in the presence of two equivalents of tert-butylisocyanide. The reaction proceeds via the reduction of copper and the formation of (CN)(2). The compound shows a tetrahedrally surrounded Cu-I centre, with the Cu I ion and the water O atom being situated on crystallographic twofold axes. The crystal structure contains infinite chains of alternating solvent molecules and Cl- anio...The title compound, [Cu(C5H9N)(4)] Cl (.) H2O, was obtained from the reaction of copper(II) chloride hydrate with KCN in the presence of two equivalents of tert-butylisocyanide. The reaction proceeds via the reduction of copper and the formation of (CN)(2). The compound shows a tetrahedrally surrounded Cu-I centre, with the Cu I ion and the water O atom being situated on crystallographic twofold axes. The crystal structure contains infinite chains of alternating solvent molecules and Cl- anions, with additional weak C - H (...) Cl or C-H (...) O interactions with the [Cu((CNBu)-Bu-t)(4)] cations. » weiterlesen» einklappen

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