Tetrakis(tert-butyl isocyanide-2 kappa C)dichloro-1 kappa Cl,3 kappa Cl-di-mu-cyano-1 kappa N : 2 kappa C;2 kappa C : 3 kappa N-bis[1,3(eta 4)-cycloocta-1,5-diene]dirhodium(I)ruthenium(II)
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. Bd. 61. 2005 S. M2130 - M2132
Erscheinungsjahr: 2005
ISBN/ISSN: 1600-5368
Publikationstyp: Zeitschriftenaufsatz
Doi/URN: 10.1107/S1600536805030461
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Inhaltszusammenfassung
The title compound, [ Rh2Ru( CN) Cl-2(2)( C8H12)(2)( C5H9N)(4)], was obtained from the reaction of the chloro( 1,5-cyclooctadiene) rhodium( I) dimer with trans-dicyanotetra( tert-butyl isocyanide) ruthenium( II) by cleavage of the chloro bridges in the dimeric rhodium starting complex. The molecular structure shows the Ru atom in a nearly ideal octahedral coordination geometry, whereas the Rh atoms are situated in square-planar ligand environments. The central ruthenium ion is located on a cr...The title compound, [ Rh2Ru( CN) Cl-2(2)( C8H12)(2)( C5H9N)(4)], was obtained from the reaction of the chloro( 1,5-cyclooctadiene) rhodium( I) dimer with trans-dicyanotetra( tert-butyl isocyanide) ruthenium( II) by cleavage of the chloro bridges in the dimeric rhodium starting complex. The molecular structure shows the Ru atom in a nearly ideal octahedral coordination geometry, whereas the Rh atoms are situated in square-planar ligand environments. The central ruthenium ion is located on a crystallographic twofold axis. The crystal structure is realized by infinite chains of the trinuclear complex units which are connected by C - H (...) Cl interactions. These chains are further linked by another C - H (...) Cl interaction to produce the observed three-dimensional structure. » weiterlesen» einklappen
