Inhaltszusammenfassung

The title compound, [ Mo( C5H9N) (3)( CO) (3)], was produced from Mo( CO) (6) and tert- butyl isocyanide in the presence of 10 atm of carbon monoxide ( 1 atm = 101325 Pa). The octahedral complex shows a facial arrangement of the ligands, the Mo - C distances of the isocyanide ligands being about 0.15 angstrom longer than the corresponding bond lengths of the carbonyl ligands. The crystal structure is influenced by one short C - H center dot center dot center dot center dot O contact, resultin...The title compound, [ Mo( C5H9N) (3)( CO) (3)], was produced from Mo( CO) (6) and tert- butyl isocyanide in the presence of 10 atm of carbon monoxide ( 1 atm = 101325 Pa). The octahedral complex shows a facial arrangement of the ligands, the Mo - C distances of the isocyanide ligands being about 0.15 angstrom longer than the corresponding bond lengths of the carbonyl ligands. The crystal structure is influenced by one short C - H center dot center dot center dot center dot O contact, resulting in infinite chains which are interconnected by additional weak C - H center dot center dot center dot center dot O interactions. » weiterlesen» einklappen

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