trans-dicyanotetrakis(2-isocyano-2,4,4-trimethylpentane)ruthenium(II)
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE. Bd. 62. 2006 S. M1514 - M1516
Erscheinungsjahr: 2006
ISBN/ISSN: 1600-5368
Publikationstyp: Zeitschriftenaufsatz
Doi/URN: 10.1107/S1600536806021532
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Inhaltszusammenfassung
In the centrosymmetric title compound, [Ru(CN)(2)(C9H17N)(4)], the central Ru atom is octahedrally coordinated by four isocyanide and two cyanide ligands in a trans configuration. The corresponding cis isomer, which is also produced in the reaction of Ru-3(CO)(12) with isooctylisocyanide, is not configurationally stable and slowly isomerizes into the trans isomer in solution.
