Inhaltszusammenfassung

N,N'-(4-methyl-4H-1,3,4-oxadiazine-5,6-diylidene)-bis-aniline derivatives react with Fe(2)(CO)(9) to give dinuclear iron carbonyl complexes. One of the iron atoms is bonded symmetrically to both exocyclic imine nitrogen atoms. The second iron atom shows a side-on coordination towards the C=N bond next to the oxadiazine oxygen atom. In addition, the iron atoms are connected via a metal metal bond. The same oxadiazine derivatives produce chiral spiro-lactams in a ruthenium catalyzed formal [2+2...N,N'-(4-methyl-4H-1,3,4-oxadiazine-5,6-diylidene)-bis-aniline derivatives react with Fe(2)(CO)(9) to give dinuclear iron carbonyl complexes. One of the iron atoms is bonded symmetrically to both exocyclic imine nitrogen atoms. The second iron atom shows a side-on coordination towards the C=N bond next to the oxadiazine oxygen atom. In addition, the iron atoms are connected via a metal metal bond. The same oxadiazine derivatives produce chiral spiro-lactams in a ruthenium catalyzed formal [2+2+1] cycloaddition reaction with carbon monoxide and ethylene. (C) 2009 Elsevier B.V. All rights reserved. » weiterlesen» einklappen

Autoren