Inhaltszusammenfassung

The syntheses of the new and partially known vanadium(III)-silanolate complexes [{V((OSiMe2Bu)-Bu-t)(3)}(2)(THF)] (1), [Li(THF)(2)V((OSiMe2Bu)-Bu-t)(4)] (2), [V((OSiMe2Bu)-Bu-t)(lut)] (3), V(OSiPh3)(3)(THF)(3) (4), [Li(THF)(4)][V(OSiPh3)(4)] (THF)(2) (5), [Li(DME)VMes((OSiMe2Bu)-Bu-t)(3)] (7), [Li(THF)(4)][VMes .(OSiPh3)(3)] (8), [Li(THF)(4)][VMes(3)((OSiMe2Bu)-Bu-t)] (9), and Na[VMes(3)(OSiPh3)](THF)(4) (10) as well as the vanadium(IV) compounds [V(OSiPh3)(4)] (6), [VMes(3)((OSiMe2Bu)-Bu-t)]...The syntheses of the new and partially known vanadium(III)-silanolate complexes [{V((OSiMe2Bu)-Bu-t)(3)}(2)(THF)] (1), [Li(THF)(2)V((OSiMe2Bu)-Bu-t)(4)] (2), [V((OSiMe2Bu)-Bu-t)(lut)] (3), V(OSiPh3)(3)(THF)(3) (4), [Li(THF)(4)][V(OSiPh3)(4)] (THF)(2) (5), [Li(DME)VMes((OSiMe2Bu)-Bu-t)(3)] (7), [Li(THF)(4)][VMes .(OSiPh3)(3)] (8), [Li(THF)(4)][VMes(3)((OSiMe2Bu)-Bu-t)] (9), and Na[VMes(3)(OSiPh3)](THF)(4) (10) as well as the vanadium(IV) compounds [V(OSiPh3)(4)] (6), [VMes(3)((OSiMe2Bu)-Bu-t)] (11) and [VMes(3)(OSiPh3)] (12) are reported. In most cases the vanadium atom displays a coordination number of four. The dimeric structure of 1 with coordination numbers of four and five, respectively, has been deduced from molecular mass measurements, mass spectrometry and its magnetic properties. The crystal structures of compounds 2, 4, 5, 9 and 11 were resolved. Complex 2 resembles a bridged contact ion pair in which both metal centres are in a tetrahedral coordination environment. In 4 the ligands are arranged trigonal bipyramidally with the THF molecules in the axial positions. Complexes 5 and 9 crystallize in separated ion paires with the vanadium in a tetrahedral coordination sphere. The crystal structure of 11 is analogous to that of 9 but with consequences due to the higher oxidation state. Oxidation of the vanadates(III), e.g. 5, 9 and 10, yields the corresponding vanadium(IV) compounds 6, 11 and 12. » weiterlesen» einklappen

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