Dewetting at the polymer-polymer interface : thickness dependence
Langmuir. Bd. 17. H. 20. Washington, DC: ACS Publ. 2001 S. 6269 - 6274
Erscheinungsjahr: 2001
ISBN/ISSN: 1520-5827 ; 0743-7463
Publikationstyp: Zeitschriftenaufsatz
Sprache: Englisch
Doi/URN: 10.1021/la010585q
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Inhaltszusammenfassung
We have used optical microscopy and scanning force microscopy to study the dewetting of polystyrene from poly(methyl methacrylate) on silicon substrates as a function of film thickness. We have performed measurements for bilayers with a lower layer more viscous than the upper layer, as well as for the opposite situation. For a solidlike (highly viscous) lower layer, the dewetting speed is constant and independent of the thickness of the polystyrene film. However, for a liquidlike lower layer,...We have used optical microscopy and scanning force microscopy to study the dewetting of polystyrene from poly(methyl methacrylate) on silicon substrates as a function of film thickness. We have performed measurements for bilayers with a lower layer more viscous than the upper layer, as well as for the opposite situation. For a solidlike (highly viscous) lower layer, the dewetting speed is constant and independent of the thickness of the polystyrene film. However, for a liquidlike lower layer, the radius of the dewetted holes grows as t2/3, where t is the annealing time, and depends on the thickness of both layers. The absolute values of the dewetting speed are in reasonable agreement with theoretical predictions.» weiterlesen» einklappen
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Klassifikation
DDC Sachgruppe:
Physik