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Dewetting at the polymer-polymer interface : thickness dependence

Langmuir. Bd. 17. H. 20. Washington, DC: ACS Publ. 2001 S. 6269 - 6274

Erscheinungsjahr: 2001

ISBN/ISSN: 1520-5827 ; 0743-7463

Publikationstyp: Zeitschriftenaufsatz

Sprache: Englisch

Doi/URN: 10.1021/la010585q

Volltext über DOI/URN

Geprüft:Bibliothek

Inhaltszusammenfassung


We have used optical microscopy and scanning force microscopy to study the dewetting of polystyrene from poly(methyl methacrylate) on silicon substrates as a function of film thickness. We have performed measurements for bilayers with a lower layer more viscous than the upper layer, as well as for the opposite situation. For a solidlike (highly viscous) lower layer, the dewetting speed is constant and independent of the thickness of the polystyrene film. However, for a liquidlike lower layer,...We have used optical microscopy and scanning force microscopy to study the dewetting of polystyrene from poly(methyl methacrylate) on silicon substrates as a function of film thickness. We have performed measurements for bilayers with a lower layer more viscous than the upper layer, as well as for the opposite situation. For a solidlike (highly viscous) lower layer, the dewetting speed is constant and independent of the thickness of the polystyrene film. However, for a liquidlike lower layer, the radius of the dewetted holes grows as t2/3, where t is the annealing time, and depends on the thickness of both layers. The absolute values of the dewetting speed are in reasonable agreement with theoretical predictions.» weiterlesen» einklappen

Autoren


Wang, Chun (Autor)
Krausch, Georg (Autor)
Geoghegan, Mark (Autor)

Klassifikation


DDC Sachgruppe:
Physik